H412: indicazione di pericolo CLP, classe associata e sostanze

L'indicazione di pericolo H412 è uno dei codici H del Regolamento CLP (CE) n. 1272/2008: «Nocivo per gli organismi acquatici con effetti di lunga durata.». Nelle voci dell'Allegato VI, il codice H412 è abbinato in modo prevalente alla classe di pericolo Pericoloso per l’ambiente acquatico – cronico (codice Aquatic Chronic, categorie Aquatic Chronic 3), un pericolo di tipo ambiente. In questa pagina trovi il testo ufficiale, a quale classe è collegata, il pittogramma tipico e un elenco di sostanze con classificazione armonizzata che la riportano.

Che cos'è l'indicazione H412

Testo ufficiale dell'indicazione H412 (Allegato III del CLP): «Nocivo per gli organismi acquatici con effetti di lunga durata.»

Le indicazioni di pericolo (codici H) descrivono la natura e, se del caso, il grado del pericolo di una sostanza o miscela. Il testo ufficiale di ogni codice è stabilito dall'Allegato III del CLP, uguale per tutte le sostanze, e in etichetta va riportato per esteso. Il codice H412 si riconosce dalla classe di pericolo a cui è associato e dal pittogramma con cui compare.

Classe di pericolo associata a H412

Nelle voci dell'Allegato VI, il codice H412 è abbinato in modo prevalente alla classe di pericolo Pericoloso per l’ambiente acquatico – cronico (codice Aquatic Chronic, categorie Aquatic Chronic 3), un pericolo di tipo ambiente.

Approfondisci la classe collegata: Pericoloso per l’ambiente acquatico – cronico (CLP).

Pittogramma tipico

Le sostanze con il codice H412 riportano in genere i seguenti pittogrammi:

• GHS07 – Punto esclamativo (irritazione, tossicità acuta minore)
• GHS05 – Corrosione (corrosivi per pelle/occhi/metalli)

Sostanze con indicazione H412

Esempi di sostanze la cui classificazione armonizzata include H412. Apri la scheda per tutti i codici di classe, le indicazioni H e i pittogrammi:

• ( R )-1,2,3,4-tetrahydro-6,7-dimethoxy-1-veratryliso
• ( S )- N – tert -butyl-1,2,3,4-tetrahydro-3-isoquino
• (2-(1,3-dioxolan-2-yl)ethyl)triphenylphosphonium bro
• (3 S ,4a S ,8a S )-2-[(2 R ,3 S )-3-amino-2-hydroxy-
• (3β, 5α, 6β)-3-(acetyloxy)-5-bromo-6-hydroxy-androst
• (η-cumene)-(η-cyclopentadienyl)iron(II) hexafluoroan
• (η-cumene)-(η-cyclopentadienyl)iron(II) trifluoromet
• 1,1,2,2-tetrabromoethane
• 1,1-dichloroethane
• 1,1-dichloropropene
• 1,2,3,6-tetrahydrophthalic anhydride
• 1,2-dibromo-3-chloropropane
• 1,2-dichloroethylene
• 1,3,5-tris(oxiranylmethyl)-1,3,5-triazine-2,4,6(1 H
• 1,3-bis(vinylsulfonylacetamido)propane
• 1,4,7,10-tetraazacyclododecane disulfate
• 1-(1-naphthylmethyl)quinolinium chloride
• 1-(3-phenylpropyl)-2-methylpyridinium bromide
• 1-butyl-2-methylpyridinium bromide
• 1-cyclopropyl-6,7-difluoro-1,4-dihydro-4-oxoquinolin
• 1-methoxy-2-propylamine
• 2'-(2-cyano-4,6-dinitrophenylazo)-5'-( N, N -dipropy
• 2,2'-dimethyl-2,2'-azodipropiononitrile
• 2,2-bis(hydroxymethyl)butanoic acid
• 2,2-dimethyl 3-methyl-3-butenyl propanoate
• 2,3-dibromopropan-1-ol
• 2,3-dichloropropene
• 2,4-D (ISO)
• 2,5-bis-isocyanatomethyl-bicyclo[2.2.1]heptane
• 2,5-dibutoxy-4-(morpholin-4-yl)benzenediazonium 4-me
• 2,6-dinitrotoluene
• 2,7,11-trimethyl-13-(2,6,6-trimethylcyclohex-1-en-1-
• 2-( O -aminooxy)ethylamine dihydrochloride
• 2-((4-amino-2-nitrophenyl)amino)benzoic acid
• 2-((4-methyl-2-nitrophenyl)amino)ethanol
• 2-(2-bromoethoxy)anisole
• 2-(3-chloropropyl)-2,5,5-trimethyl-1,3-dioxane
• 2-(3-iodoprop-2-yn-1-yloxy)ethyl phenylcarbamate
• 2-[(2-[2-(dimethylamino)ethoxy]ethyl)methylamino]eth
• 2-amino-2-methylpropanol
• 2-amino-4,6-dinitrophenol
• 2-amino-4,6-dinitrophenol
• 2-aminosulfonyl- N, N -dimethylnicotinamide
• 2-benzyl-2-methyl-3-butenitrile
• 2-butyl-2-ethyl-1,5-diaminopentane
• 2-chloro- p -toluenesulfochloride
• 2-chloro-5- sec -hexadecylhydroquinone
• 2-chloro-5-methyl-pyridine
• 2-ethylhexyl[[[3,5-bis(1,1-dimethylethyl)-4-hydroxyp
• 2-fluoro-5-trifluoromethylpyridine
• 2-hydroxymethyl-9-methyl-6-(1-methylethyl)-1,4-dioxa
• 2-methyl- m -phenylene diisocyanate
• 2-methyl-1-pentylpyridinium bromide
• 2-nitro- p -anisidine
• 2-piperazin-1-ylethylamine
• 3,5-dichloro-2,4-difluorobenzoyl fluoride
• 3,5-dinitrotoluene
• 3,6-diazaoctanethylenediamin
• 3,6-dichloro- o -anisic acid, compound with dimethyl
• 3-( N -methyl- N -(4-methylamino-3-nitrophenyl)amino
• 3-((2-nitro-4-(trifluoromethyl)phenyl)amino)propane-
• 3-((4-(bis(2-hydroxyethyl)amino)-2-nitrophenyl)amino
• 3-(2-ethylhexyloxy)propane-1,2-diol
• 3-(3-methylpent-3-yl)isoxazol-5- ylamine
• 3-chloro-5-trifluoromethyl-2- pyridylamine
• 3-cyano-3,5,5-trimethylcyclohexanone
• 4'-fluoro-2,2-dimethoxyacetophenone
• 4,4'-methylenebis( N , N '-dimethylcyclohexanamine
• 4,4'-methylenebis(2,6-dimethylphenyl cyanate)
• 4,4-dimethoxybutylamine
• 4-[ N -ethyl- N -(2-hydroxyethyl)amino]-1-(2-hydroxy
• 4-[3-(diethoxymethylsilylpropoxy)-2,2,6,6-tetramethy
• 4-ethylamino-3-nitrobenzoic acid
• 4-propylcyclohexanone
• 5- tert -butyl-3-isoxazolylamine hydrochloride
• 5-chloro-1,3-dihydro-2 H -indol-2-one
• 5-chloro-2,3-difluoropyridine
• 5-nitro- o -toluidine
• 5-thiazolylmethanol
• 5-{4-[5-amino-2-[4-(2-sulfoxyethylsulfonyl)phenylazo
• 6-dimethylaminohexan-1-ol
• 6-phenyl-1,3,5-triazine-2,4- diyldiamine
• 7-amino-3-((5-carboxymethyl-4- methyl-1,3-thiazol-2-
• 7-chloro-1-cyclopropyl-6-fluoro-1,4-dihydro-4-oxoqui
• [ R -( R *, S *)]-[[2-methyl-1-(1-oxopropoxy)propoxy
• [2-[(4-nitrophenyl)amino]ethyl]urea
• alkali salts and alkali earth salts of thiocyanic ac
• allyl glycidyl ether
• benazolin (ISO)
• benzyldimethylamine
• biphenyl-2-ylamine
• bis(1-methylethyl)-dimethoxysilane
• bis(2,2,6,6-tetramethyl-4-piperidyl) succinate
• bis(4-(1,2-bis(ethoxycarbonyl)ethylamino)-3-methylcy
• bis(4-dodecylphenyl)iodonium hexafluoroantimonate
• brucine
• brucine sulphate
• butyl glycidyl ether
• carbon tetrachloride
• chlorocresol
• chloroethane
• coumachlor (ISO)
• coumafuryl (ISO)
• cyanamide
• cyclopentane
• dalapon
• di- n -butyl ether
• dibromomethane
• dimethyl (3-methyl-4-(5-nitro-3-ethoxycarbonyl-2-thi
• diphenamid (ISO)
• disodium 1-amino-4-(4-benzenesulphonamido-3-sulphona
• disodium S , S -hexane-1,6-diyldi(thiosulphate) dihy
• ethyl 1-ethyl-6,7,8-trifluoro-1,4-dihydro-4-oxoquino
• ethyl 2-(1-cyanocyclohexyl)acetate
• ethyl 2-(3-nitrobenzylidene)acetoacetate
• ethyl-2-chloro-2,2-diphenylacetate
• fenaminosulf (ISO)
• furalaxyl (ISO)
• furan
• hexakis(tetramethylammonium) 4,4'-vinylenebis((3-sul
• hexasodium tungstate hydrate
• hydrazine bis(3-carboxy-4-hydroxybenzensulfonate)
• imazapyr (ISO)
• isobutylidene-(2-(2-isopropyl-4,4-dimethyloxazolidin
• isoprene (stabilised) 2-methyl-1,3-butadiene
• lithium bis(trifluoromethylsulfonyl)imide
• lithium sodium (4-((5-chloro-2-hydroxyphenyl)azo)-2,
• m -bis(2,3-epoxypropoxy)benzene
• Main component: acetoacetic acid anilide/3-amino-1-h
• menazon (ISO)
• mepiquat chloride (ISO)
• metalaxyl (ISO)
• metaldehyde (ISO)
• methyl ( R )-2-(4-hydroxyphenoxy)propionate
• methyl 2 R ,3 S -(-)-3-(4-methoxyphenyl)oxiranecarbo
• monosodium aqua-[5-[[2,4-dihydroxy-5-[(2-hydroxy-3,5
• morfamquat (ISO)
• morfamquat dichloride
• N , N '—1,6-hexanediylbis( N -(2,2,6,6-tetramethyl-p
• N , N -dimethyl-m-toluidine
• N -(2',6'-dimethylphenyl)-2-piperidinecarboxamide hy
• N -[3-[(2-acetyloxy)ethyl](phenyl-methyl)amino]-4-me
• N -butyl-2-(4-morpholinylcarbonyl)benzamide
• N -butyl-3-(2-chloro-4-nitrophenylhydrazono)-1-cyano
• N -methyl- o -toluidine
• N -methyl-4-( p -formylstyryl)pyridinium methylsulfa
• N — tert -pentyl-2-benzothiazolesulfenamide
• N, N -diethyl- N',N' -dimethylpropan-1,3-diyl-diamin
• N, N -hydrazinodiacetic acid
• N, N' -diphenyl- p -phenylenediamine
• nitrobenzene
• o-nitroaniline
• octasodium 2-(6-(4-chloro-6-(3-( N -methyl- N -(4-ch
• oxycarboxin (ISO)
• oxydiethylene dinitrate
• oxydiethylene dinitrate
• pentasodium 4-amino-6-(5-(4-(2-ethyl-phenylamino)-6-
• pentasodium bis{7-[4-(1-butyl-5-cyano-1,2-dihydro-2-
• phenyl glycidyl ether
• potassium 2-hydroxycarbazole-1-carboxylate
• potassium N -(4-fluorophenyl)glycinate
• potassium sodium 6,13-dichloro-3,10-bis{2-[4-[3-(2-h
• propylenethiourea
• prothoate (ISO)
• pyrogallol
• pyroquilon (ISO)
• R, R -2-hydroxy-5-(1-hydroxy-2-(4-phenylbut-2-ylamin
• reaction mass of 2-acryloyloxyethyl hydrogen cyclohe
• reaction mass of 7-[4-(3-diethylaminopropylamino)-6-
• reaction mass of isomers of: sodium phenethylnaphtha
• reaction mass of isomers of: α-((dimethyl)biphenyl)-
• reaction mass of: (3 R )-[1 S -(1α,2α, 6β-((2 S )-2-
• reaction mass of: 1,3,5-tris(3-aminomethylphenyl)-1,
• reaction mass of: 2-chloro-5- sec -tetradecylhydroqu
• reaction mass of: 2-methoxy-4-(tetrahydro-4-methylen
• reaction mass of: 3-[(4-amino-2-chloro-5-nitrophenyl
• reaction mass of: ammonium-1,2-bis(hexyloxycarbonyl)
• reaction mass of: bis(tris(2-(2-hydroxy(1-methyl)eth
• reaction mass of: butan-2-one oxime
• reaction mass of: cis-(5-ammonium-1,3,3-trimethyl)-c
• reaction mass of: disodium 4-(3-ethoxycarbonyl-4-(5-
• reaction mass of: sodium/potassium 7-[[[3-[[4-((2-hy
• reaction mass of: trans -2-(1-methylethyl)-1,3-dioxa
• reaction mass of: trilithium 4-amino-3-((4-((4-((2-a
• reaction mass of: trisodium 4-benzoylamino-6-(6-ethe
• reaction mass of: trisodium N (1')- N (2): N (1''')-
• reaction product of: 2-[[4-amino-2-ureidophenylazo]-
• Reaction product of: polyethylene-polyamine-(C 16 -C
• red phosphorus
• salts of thiocyanic acid, with the exception of thos
• sodium (1-(5-(4-(4-anilino-3-sulphophenylazo)-2-meth
• sodium 2-anilino-5-(2-nitro-4-( N -phenylsulfamoyl))
• sodium 2-ethylhexanolate
• sodium 3,5-dichloro-2-(5-cyano-2,6-bis(3-hydroxyprop
• sodium 4-[4-(4-hydroxyphenylazo)phenylamino]-3-nitro
• sodium cyanate
• sulphamidic acid
• tert -butyl (5 S ,6 R ,7 R )-3-bromomethyl-5,8-dioxo
• tetra-ammonium 2-[6-[7-(2-carboxylato-phenylazo)-8-h
• tetrahydrothiophene
• tetrahydrothiopyran-3-carboxaldehyde
• tetrakis(tetramethylammonium) 6-amino-4-hydroxy-3-(7
• tetrakis(tetramethylammonium)3,3'-(6-(2-hydroxyethyl
• tetrasodium ( c -(3-(1-(3-( e -6-dichloro-5-cyanopyr
• tetrasodium 1,2-bis(4-fluoro-6- [5-(1-amino-2-sulfon
• tetrasodium [7-(2,5-dihydroxy-K O 2-7-sulfonato-6-[4
• thioacetamide
• thiocyanic acid
• thionyl chloride, reaction products with 1,3,4-thiad
• tin tetrachloride
• trichloroethylene
• trifluoroacetic acid . . . %
• trilithium bis(4-((4-(diethylamino)-2-hydroxyphenyl)
• tris(2-hydroxyethyl)ammonium 7-{4-[4-(2-cyanoamino-4
• tris(tetramethylammonium) 5-hydroxy-1-(4-sulphonatop
• trisodium bis(2-(5-chloro-4-nitro-2-oxidophenylazo)-
• trisodium bis[(3'-nitro-5'-sulfonato(6-amino-2-[4-(2
• trisodium N, N -bis(carboxymethyl)-β-alanine
• valeric acid
• vanadyl pyrophosphate

Dove compare H412

Il codice H412 va riportato per esteso sull'etichetta CLP del prodotto, insieme a pittogramma, avvertenza e consigli di prudenza (P), e nella sezione 2 della scheda dati di sicurezza. Per le miscele, la presenza dell'indicazione dipende dalla concentrazione della sostanza e dagli eventuali limiti specifici.

Indicazioni di pericolo correlate

Altri codici H dello stesso tipo di pericolo (ambiente):

• H410
• H362
• H242
• H411
• H400
• H413

Fonti

Codici delle indicazioni di pericolo secondo gli Allegati III e VI del Regolamento (CE) n. 1272/2008 (CLP). Gli abbinamenti classe–codice e gli elenchi di sostanze derivano dalla Tabella 3.1 dell'Allegato VI; il testo ufficiale di H412 è quello dell'Allegato III. Verifica sempre la versione consolidata vigente e l'inventario C&L dell'ECHA.

Domande frequenti

A quale pericolo corrisponde il codice H412?

Nelle voci armonizzate H412 è abbinato soprattutto alla classe Pericoloso per l’ambiente acquatico – cronico (Aquatic Chronic), un pericolo di tipo ambiente. Il testo ufficiale per esteso è nell'Allegato III del CLP.

Dove trovo il testo completo di H412?

Nell'Allegato III del CLP: è uguale per tutte le sostanze e va riportato per esteso in etichetta accanto al pittogramma.

Quante sostanze hanno l'indicazione H412?

Nella Tabella 3.1 dell'Allegato VI il codice H412 compare in numerose voci: in questa pagina ne trovi un elenco collegato alle relative schede.

H412 compare sempre da solo?

No: una sostanza può avere più indicazioni di pericolo. In etichetta vanno riportate tutte quelle pertinenti, con i relativi pittogrammi e consigli di prudenza.