Classificazione ed etichettatura CLP
Classificare ed etichettare i prodotti chimici secondo il Regolamento CLP.
In sintesi
- Indica fiamma (infiammabili).
- No: in etichetta va accompagnato da avvertenza, indicazioni di pericolo (H) e consigli di prudenza (P) coerenti con la classificazione completa del prodotto.
- Nove (da GHS01 a GHS09).
- In questa pagina trovi gli esempi collegati alle schede; l’elenco completo è nell’elenco delle schede CLP per sostanza.
Il pittogramma di pericolo GHS02 del sistema GHS/CLP rappresenta Fiamma (infiammabili). Compare sull'etichetta dei prodotti chimici classificati nelle relative classi di pericolo. In questa pagina trovi cosa indica, le classi di pericolo che lo richiedono e un elenco di sostanze con classificazione armonizzata che lo riportano.
Cosa indica il pittogramma GHS02
Il pittogramma GHS02 (Fiamma (infiammabili)) è uno dei nove pittogrammi di pericolo del CLP. Ogni pittogramma è un rombo rosso con simbolo nero su fondo bianco e segnala una o più famiglie di pericolo. Va sempre accompagnato dall'avvertenza («Pericolo» o «Attenzione»), dalle indicazioni di pericolo (codici H) e dai consigli di prudenza (P).
Classi di pericolo che richiedono il GHS02
Tra le sostanze con classificazione armonizzata, il pittogramma GHS02 ricorre soprattutto per le seguenti classi di pericolo:
| Classe di pericolo | Codice | Sostanze |
|---|---|---|
| Liquido infiammabile | Flam. Liq. | 231 |
| Tossicità acuta | Acute Tox. | 213 |
| Cancerogenicità | Carc. | 192 |
| Gas infiammabile | Flam. Gas | 178 |
| Gas sotto pressione | Press. Gas | 178 |
| Mutagenicità sulle cellule germinali | Muta. | 165 |
| Pericoloso per l’ambiente acquatico – cronico | Aquatic Chronic | 101 |
| Tossicità specifica per organi bersaglio – esposizione singola | STOT SE | 91 |
| Corrosione della pelle | Skin Corr. | 74 |
| Irritazione cutanea | Skin Irrit. | 66 |
Sostanze con il pittogramma GHS02
Esempi di sostanze la cui classificazione armonizzata prevede questo pittogramma. Apri la scheda per i dettagli:
- ( S )- sec -butylamine
- ( S )-methyl-2-chloropropionate
- (ethyl-3-oxobutanoato- O '1, O '3)(2-dimethylaminoet
- 1,1-dichloroethane
- 1,1-dichloroethylene
- 1,1-dichloropropene
- 1,1-diethoxyethane
- 1,2,3,4-tetrahydro-1-naphthyl hydroperoxide
- 1,2,4-trimethylbenzene
- 1,2-dichloroethane
- 1,2-dichloroethylene
- 1,2-dichloropropane
- 1,2-dimethoxyethane
- 1,2-epoxybutane
- 1,3,5-trioxan
- 1,3-butadiene
- 1,3-di(prop-2,2-diyl)benzene bis(neodecanoylperoxide
- 1,3-dichloropropene
- 1,3-propylene oxide
- 1,4-dimethylcyclohexane
- 1,4-dioxane
- 1- tert -butoxypropan-2-ol
- 1-bromo-3,4,5-trifluorobenzene
- 1-bromo-3,5-difluorobenzene
- 1-bromopropane
- 1-chloro-2,3-epoxypropane
- 1-chloropentane
- 1-chloropropane
- 1-dimethylaminopropan-2-ol
- 1-ethoxypropan-2-ol
- 1-hydroperoxycyclohexyl 1-hydroxycyclohexyl peroxide
- 1-methoxy-2-propylamine
- 1-nitropropane
- 2,2'-dimethyl-2,2'-azodipropiononitrile
- 2,2-dimethylpropane
- 2,3-dichloropropene
- 2,4,4-trimethylpent-1-ene
- 2,4-dimethylpentan-3-one
- 2,5-dibutoxy-4-(morpholin-4-yl)benzenediazonium 4-me
- 2,6-dimethylheptan-4-one
- 2-(2-butoxyethoxy)ethyl thiocyanate
- 2-(2-hydroxy-3,5-dinitroanilino)ethanol
- 2-(isocyanatosulfonylmethyl)benzoic acid methyl este
- 2-aminoethyldimethylamine
- 2-aminopropane
- 2-bromopropane
- 2-diethylaminoethanol
- 2-dimethylaminoethanol
- 2-ethoxyethanol
- 2-ethoxyethyl acetate
- 2-fluoro-5-trifluoromethylpyridine
- 2-methoxy-1-methylethyl acetate
- 2-methoxyethanol
- 2-methoxypropanol
- 2-methoxypropyl acetate
- 2-methyl-2-azabicyclo[2.2.1]heptane
- 2-methylaziridine
- 2-methylbutan-2-ol
- 2-methylcyclohexanone
- 2-methylpropan-1-ol
- 2-methylpropan-2-ol
- 2-methylpyridine
- 2-nitropropane
- 2-phenylpropene
- 3-aminopropyldiethylamine
- 3-aminopropyldimethylamine
- 3-azidosulfonylbenzoic acid
- 3-chloro-2-methylpropene
- 3-chloro-4,5,α, α, α-pentafluorotoluene
- 3-chloropropene
- 3-hydroxy-1,1-dimethylbutyl 2-ethyl-2-methylheptanep
- 3-iodpropene
- 3a,4,7,7a-tetrahydro-4,7-methanoindene
- 4-dimethylaminobenzenediazonium 3-carboxy-4-hydroxyb
- 4-methoxy-4-methylpentan-2-one
- 4-methylpent-3-en-2-one
- 4-methylpentan-2-ol
- 4-methylpentan-2-one
- 4-methylpyridine
- 5-chloro-2,3-difluoropyridine
- 5-methylheptan-3-one
- 5-methylhexan-2-one
- 6-(nonylamino)-6-oxo-peroxyhexanoic acid
- 6-(phthalimido)peroxyhexanoic acid
- 7-methylocta-1,6-diene
- acetaldehyde
- acetic acid … %
- acetic anhydride
- acetone
- acetonitrile
- acetyl chloride
- acetylene
- acrolein
- acrylic acid
- acrylonitrile
- Alkanes, C 1-2
- Alkanes, C 1-4 , C 3 -rich
- Alkanes, C 2-3
- Alkanes, C 3-4
- Alkanes, C 4-5
- allyl alcohol
- allyl glycidyl ether
- allyl methacrylate
- allylamine
- aluminium alkyls
- aluminium phosphide
- aluminium powder (pyrophoric)
- ammonium bis(1-(3,5-dinitro-2-oxidophenylazo)-3-( N
- arsine
- benzene
- benzyldimethylamine
- bis(1-methylethyl)-dimethoxysilane
- bis(2-methoxyethyl) ether
- bis(3,5-di- tert -butylsalicylato- O 1 , O 2 )zinc
- bis(4-methylbenzoyl)peroxide
- bis(chloromethyl) ether
- bis(α,α-dimethylbenzyl) peroxide
- bis(η5-cyclopentadienyl)-bis(2,6-difluoro-3-[pyrrol-
- bromobenzene
- bromoethane
- bromoethylene
- but-1-ene
- butan-1-ol
- butan-2-ol
- butane
- butane (containing ≥ 0,1 % butadiene (203-450-8))
- butanone
- butocarboxim (ISO)
- butyl (dialkyloxy(dibutoxyphosphoryloxy))titanium (t
- butyl butyrate
- butyl chloroformate
- butyl formate
- butyl glycidyl ether
- butyl nitrite
- butylamine
- butyryl chloride
- cadmium (pyrophoric)
- calcium phosphide
- carbadox (INN)
- carbon disulphide
- carbon monoxide
- chlormethyl methyl ether
- chlorobenzene
- chloroethane
- chloromethane
- chloroprene (stabilised)
- crotonaldehyde
- Cumene
- cyclohexane
- cyclohexanone
- cyclohexylamine
- cyclopentane
- cyclopentanone
- cyclopentyl chloroformate
- cyclopropane
- di- n -butyl ether
- di- n -butylamine
- di- n -octylaluminium iodide
- di- tert -(C 12 – 14 )-alkylammonium 2-benzothiazoly
- di- tert -butyl peroxide
- dibenzoyl peroxide
- diethyl ether
- diethyl(ethyldimethylsilanolato) aluminium
- diethylamine
- diisopropyl ether
- diisopropylamine
- diketene
- dimethyl ether
- dimethyldichlorosilane
- dimethylzinc
- dipentene
- diphosphorus pentasulphide
- dipropylamine
- Distillates (petroleum), C 3-6 , piperylene-rich
- ethane
- ethanethiol
- ethyl 3,3-bis( tert -pentylperoxy)butyrate
- ethyl acetate
- ethyl acrylate
- ethyl chloroformate
- ethyl formate
- ethyl lactate
- ethyl methacrylate
- ethyl methyl ether
- ethyl nitrite
- ethyl propoxy aluminium chloride
- ethylamine
- ethylbenzene
- ethyldimethylamine
- ethylene
- ethylene oxide
- ethylenediamine
- ethyleneimine
- Foots oil (petroleum), acid-treated
- Foots oil (petroleum), clay-treated
- formic acid … %
- Fuel gases
- Fuel gases, crude oil of distillates
- furan
- Gases (petroleum), alkylation feed
- Gases (petroleum), amine system feed
- Gases (petroleum), benzene unit hydrodesulfurizer of
- Gases (petroleum), benzene unit hydrotreater depenta
- Gases (petroleum), benzene unit recycle, hydrogen-ri
- Gases (petroleum), blend oil, hydrogen-nitrogen-rich
- Gases (petroleum), butane splitter overheads
- Gases (petroleum), C 1-5 , wet
- Gases (petroleum), C 2 -return stream
- Gases (petroleum), C 2-3 –
- Gases (petroleum), C 2-4 , sweetened
- Gases (petroleum), C 3-4
- Gases (petroleum), C 3-4 , isobutane-rich
- Gases (petroleum), C 3-5 olefinic-paraffinic alkylat
- Gases (petroleum), C 4 -rich
- Gases (petroleum), C 6-8 catalytic reformer
- Gases (petroleum), C 6-8 catalytic reformer recycle
- Gases (petroleum), C 6-8 catalytic reformer recycle,
- Gases (petroleum), catalytic cracked naphtha debutan
- Gases (petroleum), catalytic cracked naphtha depropa
- Gases (petroleum), catalytic cracked overheads
- Gases (petroleum), catalytic cracker
- Gases (petroleum), catalytic cracker, C 1-5 -rich
- Gases (petroleum), catalytic cracking
- Gases (petroleum), catalytic polymd. naphtha stabili
- Gases (petroleum), catalytic reformed naphtha stripp
- Gases (petroleum), catalytic reformed straight-run n
- Gases (petroleum), catalytic reformer, C 1-4 -rich
- Gases (petroleum), catalytic-cracked gas oil depropa
- Gases (petroleum), catalytic-cracked naphtha debutan
- Gases (petroleum), crude distn. and catalytic cracki
- Gases (petroleum), crude oil fractionation off
- Gases (petroleum), deethanizer overheads
- Gases (petroleum), dehexanizer off
- Gases (petroleum), depropanizer bottoms fractionatio
- Gases (petroleum), depropanizer dry, propene-rich
- Gases (petroleum), depropanizer overheads
- Gases (petroleum), distillate unifiner desulfurizati
- Gases (petroleum), dry sour, gas-concn.-unit-off
- Gases (petroleum), fluidized catalytic cracker fract
- Gases (petroleum), fluidized catalytic cracker scrub
- Gases (petroleum), full-range straight-run naphtha d
- Gases (petroleum), gas concn. reabsorber distn.
- Gases (petroleum), gas oil diethanolamine scrubber o
- Gases (petroleum), gas oil hydrodesulfurization effl
- Gases (petroleum), gas oil hydrodesulfurization purg
- Gases (petroleum), gas recovery plant depropanizer o
- Gases (petroleum), Girbotol unit feed
- Gases (petroleum), heavy distillate hydrotreater des
- Gases (petroleum), hydrocracking depropanizer off, h
- Gases (petroleum), hydrocracking low-pressure separa
- Gases (petroleum), hydrogen absorber off
- Gases (petroleum), hydrogen-rich
- Gases (petroleum), hydrogenator effluent flash drum
- Gases (petroleum), hydrotreated sour kerosine depent
- Gases (petroleum), hydrotreated sour kerosine flash
- Gases (petroleum), hydrotreater blend oil recycle, h
- Gases (petroleum), isomerized naphtha fractionator,
- Gases (petroleum), light straight run gasoline fract
- Gases (petroleum), light straight-run naphtha stabil
- Gases (petroleum), naphtha steam cracking high-press
- Gases (petroleum), naphtha unifiner desulfurization
- Gases (petroleum), oil refinery gas distn. off
- Gases (petroleum), platformer products separator off
- Gases (petroleum), platformer stabilizer off, light
- Gases (petroleum), preflash tower off, crude distn.
- Gases (petroleum), recycle, hydrogen-rich
- Gases (petroleum), refinery
- Gases (petroleum), refinery blend
- Gases (petroleum), reformer effluent high-pressure f
- Gases (petroleum), reformer effluent low-pressure fl
- Gases (petroleum), reformer make-up, hydrogen-rich
- Gases (petroleum), reforming hydrotreater
- Gases (petroleum), reforming hydrotreater make-up, h
- Gases (petroleum), reforming hydrotreater, hydrogen-
- Gases (petroleum), residue visbaking off
- Gases (petroleum), secondary absorber off, fluidized
- Gases (petroleum), sponge absorber off, fluidized ca
- Gases (petroleum), steam-cracker C 3 -rich
- Gases (petroleum), straight-run naphtha catalytic re
- Gases (petroleum), straight-run naphtha catalytic re
- Gases (petroleum), straight-run stabilizer off
- Gases (petroleum), tar stripper off
- Gases (petroleum), thermal cracking distn.
- Gases (petroleum), unifiner stripper off
- Gases (petroleum, light steam-cracked, butadiene con
- Gases(petroleum), fluidized catalytic cracker splitt
- Gasespetroleum),deisobutanizer tower overheads
- heptan-2-one
- heptan-3-one
- heptan-4-one
- heptane
- hexan-2-one
- hexane (containing < 5 % n -hexane (203-777-6))
- hydrazine
- Hydrocarbons, C 1-3
- Hydrocarbons, C 1-4
- Hydrocarbons, C 1-4 , debutanizer fraction
- Hydrocarbons, C 1-4 , sweetened
- Hydrocarbons, C 2-4
- Hydrocarbons, C 2-4 , C 3 -rich
- Hydrocarbons, C 3
- Hydrocarbons, C 3-4
- Hydrocarbons, C 3-4 -rich, petroleum distillate
- Hydrocarbons, C 4
- Hydrocarbons, C 4 , 1,3-butadiene-and isobutene-free
- Hydrocarbons, C 4 , steam-cracker distillate
- Hydrocarbons, C 4-5
- hydrogen
- hydrogen cyanide
- hydrogen sulphide, hydrogen sulfide
- isobutyl acrylate
- isobutyl methacrylate
- isobutyl nitrite
- isobutylisopropyldimethoxysilane
- isobutyryl chloride
- isopentane
- isopentyl formate
- isoprene (stabilised) 2-methyl-1,3-butadiene
- isopropyl chloroacetate
- lithium
- magnesium alkyls
- magnesium phosphide
- magnesium powder (pyrophoric)
- magnesium, powder or turnings
- mesitylene
- metaldehyde (ISO)
- methacrylonitrile
- methane
- methanethiol
- methanol
- methenamine
- methyl acetate
- methyl acrylate
- methyl chloroacetate
- methyl chloroformate
- methyl formate
- methyl isocyanate
- methyl lactate
- methyl methacrylate
- methyl propionate
- methyl vinyl ether
- methylcyclohexane
- mono-methylamine
- mono-methylamine … %
- morpholine
- N , N -dimethylhydrazine
- n -butyl acetate
- n -butyl acrylate
- n -butyl methacrylate
- n -butyronitrile
- n -hexane
- N, N -diethyl- N',N' -dimethylpropan-1,3-diyl-diamin
- N, N,N',N' -tetramethylethylenediamine
- n-hexyllithium
- naphthenic acids, copper salts
- nitroethane
- nitromethane
- O -ethylhydroxylamine
- o -xylene
- O, O – tert -butyl O -docosyl monoperoxyoxalate
- octane
- oxalonitrile
- parathion — methyl (ISO)
- pentachlorobenzene
- pentan-3-one
- pentane
- pentane-2,4-dione
- pentanol isomers, with the exception of those specif
- pentyl formate
- pentyl nitrite
- peracetic acid … %
- Petroleum gases, liquefied
- Petroleum gases, liquefied, sweetened
- Petroleum gases, liquefied, sweetened, C 4 fraction
- Petroleum products, refinery gases
- phosphine
- piperidine
- poly-(methyl methacrylate)-co-(butylmethacrylate)-co
- potassium
- potassium iron(III) 1,3-propanediamine- N, N,N',N '-
- potassium mu-fluoro-bis(triethylaluminium)
- prop-2-yn-1-ol
- propan-1-ol
- propan-2-ol
- propanal
- propane
- propene
- propionyl chloride
- propyl acetate
- propyl chloroformate
- propyl formate
- propyl propionate
- propylene oxide
- propylenediamine
- pyridine
- R -1-chloro-2,3-epoxypropane
- R —2,3-epoxy-1-propanol
- R, R -2-hydroxy-5-(1-hydroxy-2-(4-phenylbut-2-ylamin
- Raffinates (petroleum), steam-cracked C 4 fraction c
- reaction mass of esters of 5,5',6,6',7,7'-hexahydrox
- reaction mass of: 1-methyl-1-(3-(1-methylethyl)pheny
- reaction mass of: 2,2'-bis( tert -pentylperoxy)- p –
- reaction mass of: 4,4',4''-[(2,4,6-trioxo-1,3,5(2 H
- reaction mass of: 4-(7-hydroxy-2,4,4-trimethyl-2-chr
- reaction mass of: bis(isotridecylammonium)mono(di-(4
- reaction mass of: reaction product of 4,4'-methylene
- reaction product of: (2-hydroxy-4-(3-propenoxy)benzo
- Reaction product of: 1,2,3-propanetricarboxylic acid
- Reaction product of: acetophenone, formaldehyde, cyc
- reaction product of: borax, hydrogen peroxide, aceti
- reaction products of tungsten hexachloride with 2-me
- red phosphorus
- Residues (petroleum), alkylation splitter, C 4 -rich
- S -(3-trimethoxysilyl)propyl 19-isocyanato-11-(6-iso
- sec -butyl nitrite
- sodium
- sodium ( n -butyl)x(ethyl)y-1,5-dihydro)aluminate x
- sodium 2-ethylhexanolate
- sodium dithionite
- styrene
- Tail gas (petroleum), catalytic cracked clarified oi
- Tail gas (petroleum), catalytic cracked distillate a
- Tail gas (petroleum), catalytic cracked distillate a
- Tail gas (petroleum), catalytic cracked naphtha stab
- Tail gas (petroleum), catalytic cracker refractionat
- Tail gas (petroleum), catalytic cracker, catalytic r
- Tail gas (petroleum), catalytic hydrodesulfurized na
- Tail gas (petroleum), catalytic polymn. naphtha frac
- Tail gas (petroleum), catalytic reformed naphtha fra
- Tail gas (petroleum), catalytic reformed naphtha fra
- Tail gas (petroleum), catalytic reformed naphtha sep
- Tail gas (petroleum), catalytic reformed naphtha sta
- Tail gas (petroleum), cracked distillate hydrotreate
- Tail gas (petroleum), cracked distillate hydrotreate
- Tail gas (petroleum), gas oil catalytic cracking abs
- Tail gas (petroleum), gas recovery plant
- Tail gas (petroleum), gas recovery plant deethanizer
- Tail gas (petroleum), hydrodesulfurized distillate a
- Tail gas (petroleum), hydrodesulfurized straight-run
- Tail gas (petroleum), hydrodesulfurized vacuum gas o
- Tail gas (petroleum), isomerized naphtha fractionati
- Tail gas (petroleum), light straight-run naphtha sta
- Tail gas (petroleum), propane-propylene alkylation f
- Tail gas (petroleum), saturate gas plant mixed strea
- Tail gas (petroleum), saturate gas recovery plant, C
- Tail gas (petroleum), straight-run distillate hydrod
- Tail gas (petroleum), straight-run naphtha hydrodesu
- Tail gas (petroleum), thermal cracked hydrocarbon fr
- Tail gas (petroleum), thermal-cracked distillate, ga
- Tail gas (petroleum), vacuum gas oil hydrodesulfuriz
- Tail gas (petroleum), vacuum residues thermal cracke
- tert -butyl acrylate
- tert -butyl methyl ether
- tert -butyl nitrite
- tert -butyl α, α-dimethylbenzyl peroxide
- tert -butylarsine
- tetracarbonylnickel
- tetraethyl silicate
- tetrahydrofuran
- tetrahydrothiophene
- tetrakis(trimethylhexadecylammonium) hexa-mu-oxotetr
- tetraphosphorus trisulphide
- toluene
- trialkylboranes, liquid
- trialkylboranes, solid
- trichloro(methyl)silane
- trichlorosilane
- triethylamine
- trimethyl borate
- trizinc diphosphide
- turpentine, oil
- vinyl chloride
- white phosphorus
- zinc powder — zinc dust (pyrophoric)
- zirconium powder (pyrophoric)
- α, α, α-trifluorotoluene
- α, α-dimethylbenzyl hydroperoxide
Dove compare in etichetta
Il pittogramma va apposto sull'etichetta CLP del prodotto, in dimensioni proporzionate all'imballaggio, insieme ad avvertenza, indicazioni H e consigli P. Gli stessi pericoli sono riportati nella sezione 2 della scheda dati di sicurezza. Per imballaggi molto piccoli valgono regole specifiche di etichettatura.
Tutti i nove pittogrammi di pericolo
Il CLP prevede nove pittogrammi. Ecco l'elenco completo, con la pagina di approfondimento di ciascuno:
- GHS01 – Bomba che esplode (esplosivi)
- GHS02 – Fiamma (infiammabili) (questa pagina)
- GHS03 – Fiamma su cerchio (comburenti)
- GHS04 – Bombola per gas (gas sotto pressione)
- GHS05 – Corrosione (corrosivi per pelle/occhi/metalli)
- GHS06 – Teschio e tibie incrociate (tossicità acuta)
- GHS07 – Punto esclamativo (irritazione, tossicità acuta minore)
- GHS08 – Pericolo per la salute (CMR, sensibilizzanti respiratori, aspirazione, STOT)
- GHS09 – Ambiente (pericoloso per l’ambiente acquatico)
Fonti
Pittogrammi di pericolo secondo l'Allegato V del Regolamento (CE) n. 1272/2008 (CLP). Gli elenchi di sostanze derivano dalla Tabella 3.1 dell'Allegato VI; verifica la versione consolidata vigente e l'inventario C&L dell'ECHA.
Domande frequenti
Cosa significa il pittogramma GHS02?
Indica fiamma (infiammabili). Segnala che la sostanza o la miscela presenta i pericoli delle classi associate a questo pittogramma.
Il pittogramma GHS02 basta da solo?
No: in etichetta va accompagnato da avvertenza, indicazioni di pericolo (H) e consigli di prudenza (P) coerenti con la classificazione completa del prodotto.
Quanti pittogrammi di pericolo esistono?
Nove (da GHS01 a GHS09). Un prodotto può riportarne più di uno se rientra in più classi di pericolo.
Dove trovo le sostanze che usano questo pittogramma?
In questa pagina trovi gli esempi collegati alle schede; l'elenco completo è nell'elenco delle schede CLP per sostanza.
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Avvertenza. Questo articolo ha finalità informative e divulgative e riflette la normativa vigente alla data di pubblicazione; le scadenze indicate possono essere modificate da provvedimenti successivi. Non sostituisce la verifica tecnica del singolo prodotto e del caso specifico. A cura della Redazione di ChimicaConforme.