H319: indicazione di pericolo CLP, classe associata e sostanze

L'indicazione di pericolo H319 è uno dei codici H del Regolamento CLP (CE) n. 1272/2008: «Provoca grave irritazione oculare.». Nelle voci dell'Allegato VI, il codice H319 è abbinato in modo prevalente alla classe di pericolo Irritazione oculare (codice Eye Irrit., categorie Eye Irrit. 2), un pericolo di tipo salute. In questa pagina trovi il testo ufficiale, a quale classe è collegata, il pittogramma tipico e un elenco di sostanze con classificazione armonizzata che la riportano.

Che cos'è l'indicazione H319

Testo ufficiale dell'indicazione H319 (Allegato III del CLP): «Provoca grave irritazione oculare.»

Le indicazioni di pericolo (codici H) descrivono la natura e, se del caso, il grado del pericolo di una sostanza o miscela. Il testo ufficiale di ogni codice è stabilito dall'Allegato III del CLP, uguale per tutte le sostanze, e in etichetta va riportato per esteso. Il codice H319 si riconosce dalla classe di pericolo a cui è associato e dal pittogramma con cui compare.

Classe di pericolo associata a H319

Nelle voci dell'Allegato VI, il codice H319 è abbinato in modo prevalente alla classe di pericolo Irritazione oculare (codice Eye Irrit., categorie Eye Irrit. 2), un pericolo di tipo salute.

Approfondisci la classe collegata: Irritazione oculare (CLP).

Pittogramma tipico

Le sostanze con il codice H319 riportano in genere i seguenti pittogrammi:

• GHS07 – Punto esclamativo (irritazione, tossicità acuta minore)
• GHS09 – Ambiente (pericoloso per l’ambiente acquatico)

Sostanze con indicazione H319

Esempi di sostanze la cui classificazione armonizzata include H319. Apri la scheda per tutti i codici di classe, le indicazioni H e i pittogrammi:

• ( E )-3-(2-chlorophenyl)-2-(4-fluorophenyl)propenal
• ( S )-methyl-2-chloropropionate
• (1-methyl-1,2-ethanediyl)bis[oxy(methyl-2,1-ethanedi
• (2 R ,3 R )-3-(( R )-1-( tert -butyldimethylsiloxy)e
• (2 R ,6a S ,12a S )-1,2,6,6a,12,12a-hexahydro-2-isop
• (benzothiazol-2-ylthio)methyl thiocyanate
• 1,1,2,2-tetrabromoethane
• 1,1-dichloroethane
• 1,1-diethoxyethane
• 1,1’,1’-nitrilotripropan-2-ol
• 1,2,3,4-tetrahydronaphthalene
• 1,2,4-triazole
• 1,2,4-trimethylbenzene
• 1,2-dibromoethane
• 1,2-dichlorobenzene
• 1,2-dichloroethane
• 1,2-dihydroxybenzene
• 1,2-epoxybutane
• 1,3-dichloropropene
• 1,3-diphenylguanidine
• 1,4,5,6,7,7-hexachlorobicyclo [2,2,1]hept-5-ene-2,3-
• 1,4-bis(2,3 epoxypropoxy)butane
• 1,4-dichlorobenzene
• 1,4-dioxane
• 1-(3-phenylpropyl)-2-methylpyridinium bromide
• 1-bromopropane
• 1-methyl-3-nitro-1-nitrosoguanidine
• 2,2'-(ethylenedioxy)diethyl diacrylate
• 2,2'-oxydiethyl diacrylate
• 2,2,4-trimethylhexamethylene-1,6-di-isocyanate
• 2,2-dimethyltrimethylene diacrylate
• 2,3,4,6-tetrachlorophenol
• 2,3,4-trichlorobut-1-ene
• 2,3-epoxypropan-1-ol
• 2,3-epoxypropyl-2-ethylcyclohexyl ether
• 2,4,5-T (ISO)
• 2,4,5-trichlorophenol
• 2,4,6-trichlorophenol
• 2,4,6-trimethylbenzophenone
• 2,4,6-tris(dimethylaminomethyl)phenol
• 2,4-diamino-5-methoxymethylpyrimidine
• 2,6-diamino-3,5-diethyltoluene
• 2- tert -butylaminoethyl methacrylate
• 2-(3,4-dichlorophenyl)-4-methyl-1,2,4-oxadiazolidine
• 2-(4-(3-(4-chlorophenyl)-4,5- dihydropyrazolyl)pheny
• 2-(morpholinothio)benzothiazole
• 2-(propyloxy)ethanol
• 2-amino-2-methylpropanol
• 2-aminopropane
• 2-butoxyethanol
• 2-chloro-5- sec -hexadecylhydroquinone
• 2-chlorobenzonitrile
• 2-diethylaminoethyl methacrylate
• 2-dimethylaminoethyl methacrylate
• 2-ethyl-2-[[(1-oxoallyl)oxy]methyl]-1,3-propanediyl
• 2-furaldehyde
• 2-hydroxyethyl methacrylate
• 2-hydroxypropyl methacrylate
• 2-isopropoxyethanol
• 2-isopropyl-5-methylcyclohexyloxycarbonyloxy-2-hydro
• 2-methyl- m -phenylene diisocyanate
• 2-methyl-5-phenylpentanol
• 2-methylpentane-2,4-diol
• 2-methylpropan-2-ol
• 2-methylpropyl 2-hydroxy-2-methylbut-3-enoate
• 2-methylpyridine
• 2-phenylpropene
• 3,5,5-trimethylcyclohex-2-enone
• 3,6-dichloro- o -anisic acid, compound with dimethyl
• 3-(3- tert -butyl-4-hydroxyphenyl)propionic acid
• 3-(4-chlorophenyl)-1,1-dimethyluronium trichloroacet
• 3-butoxypropan-2-ol
• 3-chloropropene
• 3-isocyanatomethyl-3,5,5-trimethylcyclohexyl isocyan
• 3-propanolide
• 3-tridecyloxy-propyl-ammonium 9-octadecenoate
• 3a,4,7,7a-tetrahydro-4,7-methanoindene
• 4 H -3,1-benzoxazine-2,4(1 H )-dione
• 4,4'-carbonimidoylbis[ N, N -dimethylaniline]
• 4,4'-methylenedi(cyclohexyl isocyanate)
• 4,4'-methylenediphenyl diisocyanate
• 4,4-dimethyl-3,5,8-trioxabicyclo[5.1.0]octane
• 4,4-isobutylethylidenediphenol
• 4-(4-nitrophenylazo)-2,6-di- sec -butyl-phenol
• 4-chloro-3,5-dimethylphenol
• 4-ethoxyaniline
• 4-isocyanatosulphonyltoluene
• 4-methylpentan-2-one
• 4-methylpyridine
• 5,5-dimethyl-perhydro-pyrimidin-2-one α-(4-trifluoro
• 5-methylheptan-3-one
• 8,9-dinorborn-5-ene-2,3-dicarboxylic anhydride
• 9,9-bis(4-hydroxyphenyl)fluorene
• acetaldehyde
• acetone
• acetonitrile
• acetophenone
• acibenzolar- S -methyl
• acrylamide
• allidochlor (ISO)
• allyl alcohol
• ammonium chloride
• anilazine (ISO)
• barium polysulphides
• benazolin (ISO)
• bentazone (ISO)
• benzene
• benzene-1,4-diamine dihydrochloride
• benzophenone-3,3',4,4'-tetracarboxylic dianhydride
• beryllium
• beryllium compounds with the exception of aluminium
• beryllium oxide
• biphenyl
• bis(2,2,6,6-tetramethyl-4-piperidyl) succinate
• bis(4-fluorophenyl)-methyl-(1,2,4-triazol-4-ylmethyl
• bis(piperidinothiocarbonyl) disulphide
• bis(α,α-dimethylbenzyl) peroxide
• bis-[4-(2,3-epoxipropoxi)phenyl]propane
• bromelain, juice
• bromoform
• bromomethane
• butan-2-ol
• butanone
• butocarboxim (ISO)
• butyl (dialkyloxy(dibutoxyphosphoryloxy))titanium (t
• butyl formate
• butyraldehyde oxime
• calcium polysulphides
• calcium sulphide
• carbon disulphide
• chloral hydrate
• chlorine
• chloroform
• chloroprene (stabilised)
• chlorphonium chloride (ISO)
• chymotrypsin
• copper sulphate
• cyanofenphos (ISO)
• cyclopentane-1,2,3,4-tetracarboxylic dianhydride
• cyclopentanone
• dazomet (ISO)
• di- n -butyl ether
• diammonium peroxodisulphate
• dibenzoyl peroxide
• dichlofluanid (ISO)
• dichlone (ISO)
• dichloro-1,3,5-triazinetrione
• dichlorophen (ISO)
• diclobutrazole (ISO)
• diethylcarbamoyl chloride
• diethyltoluamide (ISO): N,N-diethyl-m-toluamide
• dimercury dichloride
• dimethylcarbamoyl chloride
• dimethyldichlorosilane
• dimethyldioctadecylammonium hydrogen sulfate
• dinoseb (ISO)
• dipotassium peroxodisulphate
• diquat dibromide
• dodine(ISO)
• endothal (ISO)
• endothal-sodium (ISO)
• ethyl 2-cyanoacrylate
• ethyl acetate
• ethyl acrylate
• ethyl formate
• ethyl methacrylate
• ethylamine
• fenamiphos (ISO)
• fenbutatin oxide (ISO)
• fenson (ISO)
• ferbam (ISO)
• ficin
• flubenzimine (ISO)
• flumetralin (ISO)
• folpet (ISO)
• furathiocarb (ISO)
• glyoxal…%
• guaiacol
• guanidinium chloride
• heptan-3-one
• hexahydrocyclopenta[ c ]pyrrole-1-(1 H )-ammonium N
• hexamethylene diacrylate
• hexamethylene-di-isocyanate
• hexazinone (ISO)
• hexyl acrylate
• hydroxylammonium chloride
• imazapyr (ISO)
• ioxynil (ISO) 4-hydroxy-3,5-diiodobenzonitrile
• ioxynil octanoate (ISO)
• isooctyl acrylate
• isopentyl formate
• isopropyl chloroacetate
• m -bis(2,3-epoxypropoxy)benzene
• m -phenylenediamine
• m -phenylenediamine dihydrochloride
• maleic acid
• maneb (ISO)
• mecrilate
• mequinol
• methyl 2-benzylidene-3-oxobutyrate
• methyl acetate
• methyl acrylamidomethoxyacetate (containing ≥ 0,1 %
• methyl acrylate
• methyl formate
• methyl lactate
• methyl-2,3,5,6-tetrachloro-4- pyridylsulphone
• methyl-2-[(aminosulfonyl)methyl]benzoate
• methyl-phenylene diamine
• molybdenum trioxide
• monoalkyl or monoaryl or monoalkyaryl esters of meth
• monoalkylor monoaryl or monoalkylaryl esters of acry
• monobenzone
• morfamquat (ISO)
• morfamquat dichloride
• morpholine-4-carbonyl chloride
• myclobutanil(ISO)
• N , N '-bis(2,2,6,6-tetramethyl-4-piperidyl)isophtha
• N , N '-dihexadecyl- N , N '-bis(2-hydroxyethyl)prop
• N , N '—1,6-hexanediylbis( N -(2,2,6,6-tetramethyl-p
• N -2-naphthylaniline
• N -[(benzotriazole-1-yl)methyl)]4-carboxy-benzenesul
• n -butyl acrylate
• n -butyl methacrylate
• N -butyl-2-(4-morpholinylcarbonyl)benzamide
• N 5 ,N 5 -diethyltoluene-2,5-diamine monohydrochlori
• N, N -dimethylformamide
• N, N,N',N' -tetramethyldithiobis(ethylene)diamine di
• N-methyl-2-pyrrolidone
• naled (ISO)
• nitrilotriethyleneammoniopropane-2-ol 2-ethylhexanoa
• O -ethylhydroxylamine
• o -phenylenediamine
• o -phenylenediamine dihydrochloride
• o -toluidine
• oxalic acid diethylester
• p -benzoquinone
• p -phenylenediamine
• p -toluenesulphonic acid (containing a maximum of 5
• p -toluidine
• papain
• paraquat dichloride
• pentachlorophenol
• pentaerythritol tetraacrylate
• pentaerythritol triacrylate
• penthachloronaphthalene
• pentyl formate
• pepsin A
• perfluidone (ISO)
• phenylhydrazine
• potassium 2-hydroxycarbazole-1-carboxylate
• potassium chromate
• potassium sodium 5-(4-chloro-6-( N -(4-(4-chloro-6-(
• profluralin (ISO)
• propachlor (ISO)
• propan-2-ol
• propanal
• propyl acetate
• propyl formate
• propylene oxide
• proteases with the exception of those specified else
• proteinase, microbial neutral
• quinomethionate
• reaction mass of 5-heptyl-1,2,4- triazol-3-ylamine a
• reaction mass of isomers of: mono-(2-tetradecyl)naph
• reaction mass of: 2-methyl-1-(6-methylbicyclo[2.2.1]
• reaction mass of: 4-(2,2,3-trimethylcyclopent-3-en-1
• reaction mass of: 7,9,9-trimethyl-3,14-dioxa-4,13-di
• reaction mass of: diastereoisomers of 1-(1-hydroxyet
• reaction mass of: dicalcium (bis(2-hydroxy-5-tetra-p
• reaction mass of: disodium hexyldiphenyl ether disul
• reaction mass of: thiobis(4,1-phenylene)- S, S,S',S'
• Reaction product of: polyethylene-polyamine-(C 16 -C
• reaction product: bisphenol-A-(epichlorhydrin)
• rennin
• resorcinol
• sabadilla (ISO)
• salts and esters of 2,4,5-T
• salts and esters of dinoseb, with the exception of t
• salts of 4,4'-carbonimidoylbis[ N, N -dimethylanilin
• salts of ioxynil with the exception of those specifi
• secbumeton (ISO)
• silicon tetrachloride
• sodium 3-nitrobenzenesulphonate
• sodium 4-(2,4,4-trimethylpentylcarbonyloxy)benzenesu
• sodium 4-chloro-1-hydroxybutane-1-sulfonate
• sodium fluoride
• sodiumpentachlorophenolate
• styrene
• styrene oxide
• sulphamidic acid
• sulphanilic acid
• symclosene
• tert -butyl (triphenylphosphoranylidene) acetate
• tetra-ammonium 2-[6-[7-(2-carboxylato-phenylazo)-8-h
• tetrachloro- p -benzoquinone
• tetraethyl silicate
• tetrahydrofuran
• tetrahydrofuran-2,5-diyldimethanol
• tetrahydrothiophene
• tetrasodium ( c -(3-(1-(3-( e -6-dichloro-5-cyanopyr
• tetrasodium 5-benzamido-3-(5-(4-fluoro-6-(1-sulphona
• thioacetamide
• thiocarbonyl chloride
• thiram (ISO)
• toluene-2,4-diammonium sulphate
• tolylfluanid (ISO)
• tributyltin compounds, with the exception of those s
• trichloro(methyl)silane
• trichloroethylene
• trichloronitromethane
• triclosan
• trioctyltin compounds, with the exception of those s
• triphenyl phosphite
• troclosene potassium
• troclosene sodium, dihydrate
• trypsin
• turpentine, oil
• valinamide
• vanadyl pyrophosphate
• zinc 2-hydroxy-5-C 13 – 18 alkylbenzoate
• zinc bis(dibutyldithiocarbamate)
• zinc bis(diethyldithiocarbamate)
• α-bromotoluene
• ε-caprolactam

Dove compare H319

Il codice H319 va riportato per esteso sull'etichetta CLP del prodotto, insieme a pittogramma, avvertenza e consigli di prudenza (P), e nella sezione 2 della scheda dati di sicurezza. Per le miscele, la presenza dell'indicazione dipende dalla concentrazione della sostanza e dagli eventuali limiti specifici.

Indicazioni di pericolo correlate

Altri codici H dello stesso tipo di pericolo (salute):

• H350
• H318
• H373
• H335
• H334
• H361fd
• H315
• H351
• H336
• H200
• H332
• H311
• H360F
• H360Df
• H372
• H360FD
• H310
• H301
• H314
• H331
• H312
• H361d
• H302
• H330
• H340
• H317
• H300
• H341
• H360D
• H361f
• H370
• H350i
• H304

Fonti

Codici delle indicazioni di pericolo secondo gli Allegati III e VI del Regolamento (CE) n. 1272/2008 (CLP). Gli abbinamenti classe–codice e gli elenchi di sostanze derivano dalla Tabella 3.1 dell'Allegato VI; il testo ufficiale di H319 è quello dell'Allegato III. Verifica sempre la versione consolidata vigente e l'inventario C&L dell'ECHA.

Domande frequenti

A quale pericolo corrisponde il codice H319?

Nelle voci armonizzate H319 è abbinato soprattutto alla classe Irritazione oculare (Eye Irrit.), un pericolo di tipo salute. Il testo ufficiale per esteso è nell'Allegato III del CLP.

Dove trovo il testo completo di H319?

Nell'Allegato III del CLP: è uguale per tutte le sostanze e va riportato per esteso in etichetta accanto al pittogramma.

Quante sostanze hanno l'indicazione H319?

Nella Tabella 3.1 dell'Allegato VI il codice H319 compare in numerose voci: in questa pagina ne trovi un elenco collegato alle relative schede.

H319 compare sempre da solo?

No: una sostanza può avere più indicazioni di pericolo. In etichetta vanno riportate tutte quelle pertinenti, con i relativi pittogrammi e consigli di prudenza.