Sensibilizzazione cutanea (CLP): categorie, pittogramma e sostanze classificate

La classe di pericolo Sensibilizzazione cutanea (codice Skin Sens., pericolo di tipo salute) è una delle classi previste dal Regolamento CLP (CE) n. 1272/2008. In questa pagina trovi cosa significa, le categorie, il pittogramma e l'avvertenza associati e un elenco di sostanze con questa classificazione armonizzata, ciascuna collegata alla propria scheda.

Che cos'è la classe Skin Sens.

«Sensibilizzazione cutanea» è la denominazione della classe di pericolo: indica il tipo di pericolo che la sostanza presenta. La gravità è espressa dalla categoria (ad esempio 1, 1A, 1B, 2, 3): più basso è il numero, maggiore è il pericolo. A ogni categoria corrispondono un'indicazione di pericolo (codice H), un pittogramma e un'avvertenza.

Categorie della classe Skin Sens.

Tra le sostanze con classificazione armonizzata in questa classe sono presenti le seguenti categorie:

Pittogramma e avvertenza

Per questa classe, sull'etichetta CLP compaiono tipicamente i seguenti pittogrammi, con l'avvertenza Pericolo:

• GHS07 – Punto esclamativo (irritazione, tossicità acuta minore)
• GHS09 – Ambiente (pericoloso per l’ambiente acquatico)
• GHS08 – Pericolo per la salute (CMR, sensibilizzanti respiratori, aspirazione, STOT)

Sostanze classificate come sensibilizzazione cutanea

Esempi di sostanze con questa classificazione armonizzata (Allegato VI). Apri la scheda per vedere tutti i codici di classe, le indicazioni H e i pittogrammi:

• ( E )-3-(2-chlorophenyl)-2-(4-fluorophenyl)propenal
• ( E, Z )-4-chlorophenyl(cyclopropyl)ketone O -(4-nit
• ( R )-5-bromo-3-(1-methyl-2-pyrrolidinyl methyl)-1 H
• ( S )-2,3-dihydro-1 H -indole-2-carboxylic acid
• ( S )-α-(acetylthio)benzenepropanoic acid
• ( S , S )- trans -4-(acetylamino)-5,6-dihydro-6-meth
• ( Z )-1-benzo[ b ]thien-2-ylethanone oxime hydrochlo
• ((4-phenylbutyl)hydroxyphosphoryl)acetic acid
• (1 R ,4 S )-2-azabicyclo[2.2.1]hept-5-en-3-one
• (1-methyl-1,2-ethanediyl)bis[oxy(methyl-2,1-ethanedi
• (2 R ,3 R )-3-(( R )-1-( tert -butyldimethylsiloxy)e
• (2,2'-(3,3'-dioxidobiphenyl-4,4'-diyldiazo)bis(6-(4-
• (2-(aminomethyl)phenyl)acetylchloride hydrochloride
• (3'-carboxymethyl-5-(2-(3-ethyl-3 H -benzothiazol-2-
• (3β, 5α, 6β)-3-(acetyloxy)-5-bromo-6-hydroxy-androst
• (4-aminophenyl)- N -methylmethylensulfonamide hydroc
• (4-ammonio- m -tolyl)ethyl(2-hydroxyethyl)ammonium s
• (4-hydrazinophenyl)- N -methylmethanesulfonamide hyd
• (benzothiazol-2-ylthio)methyl thiocyanate
• (C 16 or C 18 -n-alkyl)(C 16 or C 18 -n-alkyl)ammoni
• (ethyl-1,2-ethanediyl)[-2-[[[(2-hydroxyethyl)methyla
• (±)-4-[2-[[3-(4-hydroxyphenyl)-1-methylpropyl]amino]
• (±)-[( R *, R *) and ( R *, S *)]-6-fluoro-3,4-dihyd
• (±)-α-[(2-acetyl-5-methylphenyl)-amino]-2,6-dichloro
• 1,1'-(1,3-phenylenedioxy)bis(3-(2-(prop-2-enyl)pheno
• 1,2,3,6-tetrahydrophthalic anhydride
• 1,2-benzisothiazol-3(2H)-one
• 1,3,5-tris(oxiranylmethyl)-1,3,5-triazine-2,4,6(1 H
• 1,3,5-tris-[(2 S and 2 R )-2,3-epoxypropyl]-1,3,5-tr
• 1,3-bis(2,3-epoxypropoxy)-2,2-dimethylpropane
• 1,3-bis(3-methyl-2,5-dioxo-1 H -pyrrolinylmethyl)ben
• 1,3-bis(vinylsulfonylacetamido)propane
• 1,3-dichloro-5-ethyl-5-methylimidazolidine-2,4-dione
• 1,3-dichloropropene
• 1,4,5,8-tetraaminoanthra quinone
• 1,4,7,10-tetrakis( p -toluensulfonyl)-1,4,7,10-tetra
• 1,4-bis(2,3 epoxypropoxy)butane
• 1,4-bis[(vinyloxy)methyl]cyclohexane
• 1,4-dichloro-2-(1,1,2,3,3,3-hexafluoropropoxy)-5-nit
• 1,4-Dicyano-2,3,5,6-tetra-chloro-benzene
• 1,4-dihydroxybenzene
• 1,6-bis(3,3-bis((1-methylpentylidenimino)propyl)urei
• 1-((2-quinolinyl-carbonyl)oxy)-2,5-pyrrolidinedione
• 1-(2-propenyl)pyridinium chloride
• 1-(3-(4-fluorophenoxy)propyl)3-methoxy-4-piperidinon
• 1-(4-(trans-4-heptylcyclohexyl)phenyl) ethanone
• 1-bromo-3,5-difluorobenzene
• 1-bromo-9-(4,4,5,5,5-pentafluoropentylthio)nonane
• 1-chloro-2,3-epoxypropane
• 1-dimethoxymethyl-2-nitro-benzene
• 1-dodecyl-2-pyrrolidone
• 1-methyltrimethylene diacrylate
• 1-octylazepin-2-one
• 2'-(2-cyano-4,6-dinitrophenylazo)-5'-( N, N -dipropy
• 2'-(4-chloro-3-cyano-5-formyl-2-thienylazo)-5'-dieth
• 2,2',2''-(hexahydro-1,3,5- triazine-1,3,5-triyl)trie
• 2,2'-(ethylenedioxy)diethyl diacrylate
• 2,2'-azobis[2-methylpropionamidine] dihydrochloride
• 2,2'-diallyl-4,4'-sulfonyldiphenol
• 2,2'-iminodiethylamine
• 2,2'-oxydiethyl diacrylate
• 2,2,6,6-tetrakis(bromomethyl)-4-oxaheptane-1,7-diol
• 2,2-(1,4-phenylene)bis((4 H —3,1-benzoxazine-4-one)
• 2,2-dibromo-2-nitroethanol
• 2,2-dimethyltrimethylene diacrylate
• 2,2-ethylmethylthiazolidine
• 2,3,4,5-tetrachlorobenzoylchloride
• 2,3,5,6-tetrahydro-2-methyl-2 H -cyclopenta[ d ]-1,2
• 2,3,5-trimethylhydroquinone
• 2,3-dichloro-5-trifluoromethyl- pyridine
• 2,3-epoxypropyl acrylate
• 2,3-epoxypropyl methacrylate
• 2,3-epoxypropyl-2-ethylcyclohexyl ether
• 2,4,6-trichloro-1,3,5-triazine
• 2,4-D (ISO)
• 2,4-dichloro-3-ethyl-6-nitrophenol
• 2,4-difluoro-α-(1 H -1,2,4-triazol-1-yl)acetophenone
• 2,4-dihydroxy- N -(2-methoxyphenyl)benzamide
• 2,4-dimethyl-6-(1-methyl-pentadecyl)phenol
• 2,5,7,7-tetramethyloctanal
• 2,5-bis-isocyanatomethyl-bicyclo[2.2.1]heptane
• 2,5-dibutoxy-4-(morpholin-4-yl)benzenediazonium 4-me
• 2,5-dimercaptomethyl-1,4-dithiane
• 2,6-dichloro-4-trifluoromethylaniline
• 2,7,11-trimethyl-13-(2,6,6-trimethylcyclohex-1-en-1-
• 2,9-bis(3-(diethylamino)propylsulfamoyl)quino(2,3-b)
• 2- n -butyl-benzo[ d ]isothiazol-3-one
• 2- n -hexadecylhydroquinone
• 2- tert -butylaminoethyl methacrylate
• 2-( N -benzyl- N -methylamino)ethyl 3-amino-2-buteno
• 2-( O -aminooxy)ethylamine dihydrochloride
• 2-((4-(ethyl-(2-hydroxyethyl)amino)-2-methylphenyl)a
• 2-((4-amino-2-nitrophenyl)amino)benzoic acid
• 2-((4-methyl-2-nitrophenyl)amino)ethanol
• 2-(2,4-dichlorophenyl)-2-(2-propenyl)oxirane
• 2-(2-amino-1,3-thiazol-4-yl)-( Z )-2-methoxyiminoace
• 2-(3-(prop-1-en-2-yl)phenyl)prop-2-yl isocyanate
• 2-(4-(3-(4-chlorophenyl)-2-pyra zolin-1-yl)phenylsul
• 2-(4-(diethylaminopropylcarbamoyl)phenylazo)-3-oxo-
• 2-(4-aminophenyl)-6- tert -butyl-1 H -pyrazolo[1,5-b
• 2-(diphosphonomethyl)succinic acid
• 2-(morpholinothio)benzothiazole
• 2-[[4[[4,6-bis[[3-(diethylamino)propyl]amino]-1,3,5-
• 2-alkoyloxyethyl hydrogen maleate, where alkoyl repr
• 2-aminosulfonyl- N, N -dimethylnicotinamide
• 2-bromo-1-(2-furyl)-2-nitroethylene
• 2-bromo-2-nitropropanol
• 2-butyl-2-ethyl-1,5-diaminopentane
• 2-butyl-4-chloro-5-formylimidazole
• 2-chloracetamide
• 2-chloro- p -toluenesulfochloride
• 2-chloro-4,5-difluorobenzoic acid
• 2-chloro-5- sec -hexadecylhydroquinone
• 2-chloro-6-(ethylamino)-4-nitrophenol
• 2-chloromethyl-3,4-dimethoxypyridinium chloride
• 2-cyclohexylpropanal
• 2-diethylaminoethyl methacrylate
• 2-dimethylaminoethyl methacrylate
• 2-ethoxyethyl 2-(4-(2,6-dihydro-2,6-dioxo-7-phenyl-1
• 2-ethyl-2-[[(1-oxoallyl)oxy]methyl]-1,3-propanediyl
• 2-ethylhexyl acrylate
• 2-ethylhexyl[[[3,5-bis(1,1-dimethylethyl)-4-hydroxyp
• 2-fluoro-5-trifluoromethylpyridine
• 2-hydroxy-1-methylethylacrylate
• 2-hydroxyethyl acrylate
• 2-hydroxyethyl methacrylate
• 2-hydroxyethylammonium perbromide
• 2-hydroxypropyl methacrylate
• 2-methyl- m -phenylene diisocyanate
• 2-methyl- m -phenylenediamine
• 2-methyl- p -phenylenediamine
• 2-methyl- p -phenylenediamine sulphate [1]
• 2-methyl-4-(1,1-dimethylethyl)-6-(1-methyl-pentadecy
• 2-methyl-4-phenylpentanol
• 2-methyl-5-(1,1,3,3-tetramethylbutyl)hydroquinone
• 2-naphthylamino-6-sulfomethylamide
• 2-nitro-2-phenyl-1,3-propanediol
• 2-phenylethylisocyanate
• 2-phenylthioaniline
• 2-piperazin-1-ylethylamine
• 3(or 5)-(4-( N -benzyl- N -ethylamino)-2-methylpheny
• 3,3'-dichlorobenzidine
• 3,3'-iminodi(propylamine)
• 3,4-dichloroaniline
• 3,5-bis-(tetradecyloxycarbonyl)benzenesulfinic acid
• 3,5-dichloro-2,4-difluorobenzoyl fluoride
• 3,5-dimethylbenzoyl chloride
• 3,6,9,12-tetra-azatetradecamethylenediamine
• 3,6,9-triazaundecamethylenediamine
• 3,6-diazaoctanethylenediamin
• 3,7-dimethyloctanenitrile
• 3-((4-(bis(2-hydroxyethyl)amino)-2-nitrophenyl)amino
• 3-(2-(diaminomethyleneamino)thiazol-4-ylmethylthio)p
• 3-(bis(2-ethylhexyl)amino methyl)benzothiazole-2(3 H
• 3-amino-4-hydroxy- N -(2-methoxyethyl)-benzenesulfon
• 3-aminomethyl-3,5,5-trimethylcyclohexylamine
• 3-aminopropyldiethylamine
• 3-aminopropyldimethylamine
• 3-azidosulfonylbenzoic acid
• 3-chloro-2,4-difluoronitrobenzene
• 3-chloro-2-methylpropene
• 3-cyano-3,5,5-trimethylcyclohexanone
• 3-isocyanatomethyl-3,5,5-trimethylcyclohexyl isocyan
• 3-methylaminomethylphenylamine
• 4 H -3,1-benzoxazine-2,4(1 H )-dione
• 4'-fluoro-2,2-dimethoxyacetophenone
• 4,4'-diamino-2-methylazobenzene
• 4,4'-diaminodiphenylmethane
• 4,4'-isopropylidenediphenol
• 4,4'-methylenebis(2,6-dimethylphenyl cyanate)
• 4,4'-methylenedi(cyclohexyl isocyanate)
• 4,4'-methylenedi- o -toluidine
• 4,4'-methylenediphenyl diisocyanate
• 4,4'-oxybis(ethylenethio)diphenol
• 4,4-dimethoxybutylamine
• 4,4-dimethyl-3,5,8-trioxabicyclo[5.1.0]octane
• 4- o -tolylazo- o -toluidine
• 4-( trans -4-propylcyclohexyl)acetophenone
• 4-(1(or 4 or 5 or 6)-methyl-8,9,10-trinorborn-5-en-2
• 4-(1-oxo-2-propenyl)-morpholine
• 4-(2-chloro-4-trifluoromethyl)phenoxy-2-fluoroanilin
• 4-(2-cyano-3-phenylamino acryloyloxymethyl)-cyclohex
• 4-(4-nitrophenylazo)-2,6-di- sec -butyl-phenol
• 4-[ N -ethyl- N -(2-hydroxyethyl)amino]-1-(2-hydroxy
• 4-[4-(1,3-dihydroxyprop-2-yl)phenylamino]-1,8-dihydr
• 4-[4-amino-5-hydroxy-3-(4-(2-sulfoxyethylsulfonyl)ph
• 4-amino-2-(aminomethyl)phenol dihydrochloride
• 4-amino-3-fluorophenol
• 4-benzyl-2,6-dihydroxy-4-aza-heptylene bis (2,2-dime
• 4-chloro-3,5-dimethylphenol
• 4-chloroaniline
• 4-chlorobutyl veratrate
• 4-chlorophenyl cyclopropyl ketone O -(4-aminobenzyl)
• 4-dimethylaminobenzenediazonium 3-carboxy-4-hydroxyb
• 4-ethoxyaniline
• 4-ethyl-2-methyl-2-isopentyl-1,3-oxazolidine
• 4-ethylamino-3-nitrobenzoic acid
• 4-methyl- m -phenylenediamine
• 4-methyl-8-methylenetricyclo[3.3.1.1 3,7 ]dec-2-yl a
• 4-methyl-8-methylenetricyclo[3.3.1.1 3,7 ]decan-2-ol
• 4-nonylphenol, reaction products with formaldehyde a
• 5-acetyl-3-amino-10,11-dihydro-5 H -dibenz[ b, f ]az
• 5-amino-2,4,6-triiodo-1,3-benzenedicarbonyldichlorid
• 5-bromo-8-naphtholactam
• 5-chloro-1,3-dihydro-2 H -indol-2-one
• 6-(2,3-dimethylmaleimido)hexyl methacrylate
• 6-(nonylamino)-6-oxo-peroxyhexanoic acid
• 6-docosyloxy-1-hydroxy-4-(1-(4-hydroxy-3-methylphena
• 6-fluoro-2-methyl-3-(4-methylthiobenzyl)indene
• 6-hydroxyindole
• 6-methyl-2,4-bis(methylthio)phenylene-1,3-diamine
• 7-amino-3-((5-carboxymethyl-4- methyl-1,3-thiazol-2-
• 8,9,10-trinorborn-2-yl acrylate
• 8,9,10-trinorborn-5-ene-2,3-dicarboxylic anhydride
• 8-amino-7-methylquinoline
• 9-vinylcarbazole
• [ R -( R *, S *)]-[[2-methyl-1-(1-oxopropoxy)propoxy
• [( p -tolyloxy)methyl]oxirane
• [2-[(4-nitrophenyl)amino]ethyl]urea
• acetochlor (ISO)
• acibenzolar- S -methyl
• aclonifen (ISO)
• acrylamide
• acrylonitrile
• alachlor (ISO)
• allyl glycidyl ether
• amines, polyethylenepoly-
• amitraz (ISO)
• ammonium dichromate
• atrazine (ISO)
• azinphos-methyl (ISO)
• barban (ISO)
• behenamidopropyl-dimethyl-(dihydroxypropyl) ammonium
• benomyl (ISO)
• bentazone (ISO)
• benzene-1,2,4-tricarboxylic acid 1,2-anhydride
• benzene-1,2:4,5-tetracarboxylic dianhydride
• benzene-1,4-diamine dihydrochloride
• benzo[ a ]pyrene
• benzothiazole-2-thiol
• benzyl 2,4-dibromobutanoate
• beryllium
• beryllium compounds with the exception of aluminium
• beryllium oxide
• biphenyl-2-ol
• bis( N -(7-hydroxy-8-methyl-5-phenylphenazin-3-ylide
• bis(1-methylethyl)-dimethoxysilane
• bis(2,6-dimethoxybenzoyl)-2,4,4-trimethylpentylphosp
• bis(2-ethylhexyl) dithiodiacetate
• bis(4-(1,2-bis(ethoxycarbonyl)ethylamino)-3-methylcy
• bis(4-dodecylphenyl)iodonium hexafluoroantimonate
• bis(4-hydroxy-N-methylanilinium) sulphate
• bis(dimethyl-(2-hydroxyethyl)ammonium) 1,2-ethanediy
• bis(piperidinothiocarbonyl) disulphide
• bis-[4-(2,3-epoxipropoxi)phenyl]propane
• bis[4-(ethenyloxy)butyl] 1,3-benzenedicarboxylate
• bromoacetic acid
• bromobenzylbromotoluene, reaction mass of isomers
• bromoxynil (ISO) 3,5-dibromo-4-hydroxybenzonitrile
• bromoxynil heptanoate (ISO)
• bromoxynil octanoate (ISO)
• but-2-yne-1,4-diol
• butanone oxime
• butyl glycidyl ether
• C 8-18 alkylbis(2-hydroxyethyl)ammonium bis(2-ethylh
• C.I. Disperse Yellow 3
• C.I. Solvent Yellow 14
• captafol (ISO)
• captan (ISO)
• carbendazim (ISO)
• carbosulfan (ISO)
• chloridazon (ISO)
• chlorocresol
• chlorothalonil (ISO)
• chlorpyrifos-methyl (ISO) O, O -dimethyl O -3,5,6-tr
• chromium (VI) compounds, with the exception of bariu
• chromium (VI) trioxide
• chromyl dichloride
• cis -1,2,3,6-tetrahydro-4-methylphthalic anhydride
• cis -1-(3-chloropropyl)-2,6-dimethyl-piperidin hydro
• citral
• cobalt
• cobalt dichloride
• cobalt oxide
• cobalt sulfate
• cobalt sulfide
• condensation product of: 3-(7-carboxyhept-1-yl)-6-he
• cyanamide
• cyclohexane-1,2-dicarboxylic anhydride
• cyclooct-4-en-1-yl methyl carbonate
• cyclopentyl chloroformate
• cymoxanil (ISO)
• cypermethrin cis/trans +/-80/20
• di(benzothiazol-2-yl) disulphide
• diamminediisocyanatozinc
• diammonium hexachloroplatinate
• diammonium peroxodisulphate
• diammonium tetrachloroplatinate
• dibenzoyl peroxide
• dibenzylphenylsulfonium hexafluoroantimonate
• dibutyltin hydrogen borate
• dichlofluanid (ISO)
• dichlorprop-P (ISO)
• dichlorvos (ISO)
• dichromium tris(chromate)
• diclofop-methyl (ISO)methyl 2-(4-(2,4-dichlorophenox
• dicofol (ISO)
• dicyclohexylcarbodiimide
• diethyl{4-[1,5,5-tris(4-diethylaminophenyl)penta-2,4
• dilithium disodium (5,5'-diamino-(μ-4,4'-dihydroxy-1
• dimethachlor (ISO)
• dimethyl (3-methyl-4-(5-nitro-3-ethoxycarbonyl-2-thi
• dimethyl sulphate
• dinickel trioxide
• dinocap (ISO)
• dipentene
• diphenyl(4-phenylthiophenyl)sulfonium hexafluoroanti
• dipotassium hexachloroplatinate
• dipotassium peroxodisulphate
• dipotassium tetrachloroplatinate
• diquat dibromide
• disodium 1-amino-4-(2-(5-chloro-6-fluoro-pyrimidin-4
• disodium 5-[5-[4-(5-chloro-2,6-difluoropyrimidin-4-y
• disodium hexachloroplatinate
• disodium S , S -hexane-1,6-diyldi(thiosulphate) dihy
• disodium tetrachloroplatinate
• disulfiram
• ditalimfos (ISO)
• divanadyl pyrophosphate
• DNOC (ISO)
• dodemorph (ISO)
• E -ethyl-4-oxo-4-phenylcrotonate
• edifenphos (ISO)
• esters of 2,4-D
• esters of mecoprop and of mecoprop-P
• ethidimuron (ISO)
• ethoprophos (ISO)
• ethyl 1-ethyl-6,7,8-trifluoro-1,4-dihydro-4-oxoquino
• ethyl 2-(3-nitrobenzylidene)acetoacetate
• ethyl 2-(isocyanatosulfonyl)benzoate
• ethyl 2-[4-[(6-chlorobenzoxazol-2-yl)oxy]phenoxy]pro
• ethyl 2-carboxy-3-(2-thienyl)propionate
• ethyl 3-hydroxy-5-oxo-3-cyclohexene-1-carboxylate
• ethyl acrylate
• ethyl methacrylate
• ethylene dimethacrylate
• ethylenediamine
• etridiazole (ISO)
• flufenacet (ISO)
• flumetralin (ISO)
• folpet (ISO)
• formaldehyde … %
• formaldehyde, reaction products with butylphenol
• formetanate (ISO)
• formetanate hydrochloride
• fosthiazate (ISO)
• fuberidazole (ISO)
• furathiocarb (ISO)
• glutaral
• glyoxal…%
• hafnium tetra- n -butoxide
• hexachloroplatinates with the exception of those spe
• hexachloroplatinic acid
• hexaconazole (ISO)
• hexahydro-4-methylphthalic anhydride
• hexahydrocyclopenta[ c ]pyrrole-1-(1 H )-ammonium N
• hexakis(tetramethylammonium) 4,4'-vinylenebis((3-sul
• hexamethylene diacrylate
• hexamethylene-di-isocyanate
• hexasodium (di[ N -(3-(4-[5-(5-amino-3-methyl-1-phen
• hexasodium 6,13-dichloro-3,10- bis((4-(2,5-disulfona
• hexyl acrylate
• hydrazine
• hydrazine bis(3-carboxy-4-hydroxybenzensulfonate)
• hydrazine-trinitromethane
• hydrogen sodium N -carboxylatoethyl- N -octadec-9-en
• hydroxylamine … % [> 55 % in aqueous solution]
• hydroxylammonium chloride
• hydroxyphosphonoacetic acid
• hymexazol (ISO)
• imazalil sulphate (ISO) powder
• imazalil sulphate (ISO), aqueous solution
• ioxynil octanoate (ISO)
• isazofos (ISO)
• isobutyl 3,4-epoxybutyrate
• isobutyl acrylate
• isobutyl methacrylate
• lithium 1-amino-4-(4-tert-butylanilino)anthraquinone
• lithium 3-oxo-1,2(2 H )-benzisothiazol-2-ide
• lithium sodium hydrogen 4-amino-6-(5-(5-chloro-2,6-d
• lufenuron (ISO)
• m -bis(2,3-epoxypropoxy)benzene
• m -phenylenediamine
• m -phenylenediamine dihydrochloride
• magnesium bis(( R )-2-(2,4-dichlorophenoxy)propionat
• Main component: acetoacetic acid anilide/3-amino-1-h
• malathion (ISO)
• maleic acid
• maleic anhydride
• mancozeb (ISO)
• maneb (ISO)
• mequinol
• metalaxyl (ISO)
• metam-sodium (ISO)
• methacrylonitrile
• methenamine
• methyl 2 R ,3 S -(-)-3-(4-methoxyphenyl)oxiranecarbo
• methyl 2-(2-nitrobenzylidene)acetoacetate
• methyl 2-(3-nitrobenzylidene)acetoacetate
• methyl 2-[4-(2-chloro-4-nitrophenylazo)-3-(1-oxoprop
• methyl 2-aminosulfonyl-6-(trifluoromethyl)pyridine-3
• methyl 3-(acetylthio)-2-methyl-propanoate
• methyl 3-[(dimethoxyphosphinothioyl)oxy]methacrylate
• methyl 3-isocyanatosulfonyl-2-thiophene-carboxylate
• methyl 4-bromomethyl-3-methoxybenzoate
• methyl acrylamidoglycolate (containing ≥ 0,1 % acryl
• methyl acrylate
• methyl isocyanate
• methyl isothiocyanate
• methyl methacrylate
• methyl N -[3-acetylamino)-4-(2-cyano-4-nitrophenylaz
• methyl α-((4,6-dimethoxypyrimidin-2-yl)ureidosulphon
• methyl-2,3,5,6-tetrachloro-4- pyridylsulphone
• methyl-phenylene diamine
• methylene dithiocyanate
• mixed linear and branched C 14-15 alcohols ethoxylat
• molinate (ISO)
• mono[2-(dimethylamino)ethyl]monohydrogen-2-(hexadec-
• monobenzone
• N , N '-bis{6-chloro-4-[6-(4-vinylsulfonylphenylazo)
• N , N , N ', N '-tetraglycidyl-4,4'-diamino-3,3'-die
• N , N , N , N -tetrakis(4,6-bis(butyl- ( N -methyl-2
• N -(2-(4-amino- N -ethyl- m -toluidino)ethyl)methane
• N -(2-(6-ethyl-7-(4-methylphenoxy)-1 H -pyrazolo[1,5
• N -(4-(3-(4-cyanophenyl)ureido)-3-hydroxyphenyl)-2-(
• N -2-naphthylaniline
• N -[2-(3-acetyl-5-nitrothiophen-2-ylazo)-5-diethylam
• N -[2-hydroxy-3-(C 12-16 -alkyloxy)propyl]- N -methy
• n -butyl acrylate
• n -butyl methacrylate
• N -butyl-2-(4-morpholinylcarbonyl)benzamide
• N -butyl-3-(2-chloro-4-nitrophenylhydrazono)-1-cyano
• N -cyclohexylbenzothiazole-2- sulphenamide
• N -dodecyl-[3-(4-(dimethylamino)benzamido)-propyl]di
• N -hexadecyl(or octadecyl)- N -hexadecyl (or octadec
• N -isopropyl- N' -phenyl- p -phenylenediamine
• N -methyl-4-( p -formylstyryl)pyridinium methylsulfa
• N 5 ,N 5 -diethyltoluene-2,5-diamine monohydrochlori
• N — tert -pentyl-2-benzothiazolesulfenamide
• N, N '-bis(trifluoroacetyl)- S, S '-bis-L-homocystei
• N, N -bis(2-(p-toluenesulfonyloxy)ethyl)- p -toluene
• N, N -bis(2-ethylhexyl)-((1,2,4- triazol-1-yl)methyl
• N, N -dimethyl-2-(3-(4-chloro phenyl)-4,5-dihydropyr
• N, N -hydrazinodiacetic acid
• N, N' -(2,2-dimethylpropylidene)hexamethylenediamine
• N, N' -diphenyl- p -phenylenediamine
• N, N' -ethylenebis(vinylsulfonylacetamide)
• N, N,N',N' -tetramethyldithiobis(ethylene)diamine di
• nabam (ISO)
• nickel
• nickel (II) sulfide
• nickel carbonate
• nickel dihydroxide
• nickel dioxide
• nickel monoxide
• nickel sulfate
• niline
• nitrilotriethyleneammoniopropane-2-ol 2-ethylhexanoa
• O -ethylhydroxylamine
• o -phenylenediamine
• o -phenylenediamine dihydrochloride
• octasodium 2-(6-(4-chloro-6-(3-( N -methyl- N -(4-ch
• octhilinone (ISO)
• octyl 3,4,5-trihydroxybenzoate
• oxirane, mono[(C 12 – 14 -alkyloxy)methyl] derivs.
• oxiranemethanol, 4-methylbenzene-sulfonate, ( S )-
• oxo-((2,2,6,6-tetramethylpiperidin-4-yl)amino)carbon
• p -phenylenediamine
• p -toluidine
• p -tolyl 4-chlorobenzoate
• pentaerythritol tetraacrylate
• pentaerythritol triacrylate
• pentasodium 4-amino-6-(5-(4-(2-ethyl-phenylamino)-6-
• permethrin (ISO)
• phenyl bis(2,4,6-trimethylbenzoyl)-phosphine oxide
• phenyl glycidyl ether
• phenyl N -(4,6-dimethoxypyrimidin-2-yl)carbamate
• phenylhydrazine
• phosalone (ISO)
• phoxim (ISO)
• phthalic anhydride
• piperazine
• pirimicarb (ISO)
• poly-(methyl methacrylate)-co-(butylmethacrylate)-co
• polyethlyenepolyamines with the exception of those s
• polymer of allylamine hydrochloride
• polymeric reaction product of bicyclo[2.2.1]hepta-2,
• potassium 2-(2,4-dichlorophenoxy)-( R )-propionate
• potassium chromate
• potassium dichromate
• potassium N -(4-fluorophenyl)glycinate
• potassium sodium 5-(4-chloro-6-( N -(4-(4-chloro-6-(
• propachlor (ISO)
• propiconazole (ISO)
• propyl 3,4,5-trihydroxybenzoate
• prosulfocarb (ISO)
• pyridate (ISO)
• quinomethionate
• quinoxyfen (ISO)
• quintozene (ISO)
• R -1-chloro-2,3-epoxypropane
• R, R -2-hydroxy-5-(1-hydroxy-2-(4-phenylbut-2-ylamin
• reaction mass (ratio not known) of: ammonium 1-C 14
• reaction mass of 1,1'-(methylenebis(4,1-phenylene))d
• reaction mass of 2-acryloyloxyethyl hydrogen cyclohe
• reaction mass of 5-chloro-2-methyl-2 H -isothiazol-3
• reaction mass of 7-[4-(3-diethylaminopropylamino)-6-
• reaction mass of C 12-14 – tert -alkylammonium diphe
• reaction mass of iron complexes of: 1,3-dihydroxy-4-
• reaction mass of isomers of: sodium phenethylnaphtha
• reaction mass of n -octadecylaminodiethyl bis(hydrog
• reaction mass of N,N' -ethane-1,2-diylbis(decanamide
• reaction mass of O, O '-diisopropyl (pentathio)dithi
• reaction mass of α-3-(3-(2 H -benzotriazol-2-yl)-5-
• reaction mass of: (3 R )-[1 S -(1α,2α, 6β-((2 S )-2-
• reaction mass of: 1,3,5-tris(3-aminomethylphenyl)-1,
• reaction mass of: 2,2,6,6-tetramethylpiperidin-4-yl-
• reaction mass of: 2,4,6-tri(butylcarbamoyl)-1,3,5-tr
• reaction mass of: 2-(hexylthio)ethylamine hydrochlor
• reaction mass of: 2-[ N -ethyl-4-[(5,6-dichlorobenzo
• reaction mass of: 2-chloro-5- sec -tetradecylhydroqu
• reaction mass of: 2-methoxy-4-(tetrahydro-4-methylen
• reaction mass of: 3-cyano-5-(2-cyano-4-nitro-phenyla
• reaction mass of: 3a,4,5,6,7,7a-hexahydro-4,7-methan
• reaction mass of: 4,4',4''-[(2,4,6-trioxo-1,3,5(2 H
• reaction mass of: 4-allyl-2,6-bis(2,3-epoxypropyl)ph
• reaction mass of: 5-[(4-[(7-amino-1-hydroxy-3-sulfo-
• reaction mass of: 7,9,9-trimethyl-3,14-dioxa-4,13-di
• reaction mass of: bis( N -cyclohexyl- N' -phenyleneu
• reaction mass of: butan-2-one oxime
• reaction mass of: cis-(5-ammonium-1,3,3-trimethyl)-c
• reaction mass of: dicalcium (bis(2-hydroxy-5-tetra-p
• reaction mass of: disodium (6-(4-anisidino)-3-sulfon
• reaction mass of: dodecanoic acid
• reaction mass of: dodecanoic acid (35-40 %)
• reaction mass of: N -aminoethylpiperazonium mono-2,4
• reaction mass of: sodium 1-tridecyl-4-allyl-(2 or 3)
• reaction mass of: sodium 2-(C 12-18 – n -alkyl)amino
• reaction mass of: sodium/potassium (3-(4-(5-(5-chlor
• reaction mass of: sodium/potassium 7-[[[3-[[4-((2-hy
• reaction mass of: tetradecanoic acid
• reaction mass of: tetradecanoic acid (42,5-47,5 %)
• reaction mass of: tetrasodium phosphonoethane-1,2-di
• reaction mass of: thiobis(4,1-phenylene)- S, S,S',S'
• reaction mass of: trans -(2 R )-5-acetoxy-1,3-oxathi
• reaction mass of: trisodium (2,4(or 2,6 or 4,6)-bis(
• reaction mass of: trisodium 4-benzoylamino-6-(6-ethe
• reaction mass of: trisodium 5{4-chloro-6-[2-(2,6-dic
• reaction mass of: α-[3-(3-mercaptopropanoxycarbonyla
• reaction product of ammonium molybdate and C 12 -C 2
• Reaction product of: acetophenone, formaldehyde, cyc
• Reaction product of: polyethylene-polyamine-(C 16 -C
• reaction product: bisphenol-A-(epichlorhydrin)
• reaction products of tungsten hexachloride with 2-me
• reaction products of: aniline-terephthalaldehyde- o
• resorcinol
• S -(3-trimethoxysilyl)propyl 19-isocyanato-11-(6-iso
• S -metolachlor (ISO)
• salts of 2,4-D
• salts of 3,3'-dichlorobenzidine
• salts of aniline
• salts of bromoxynil with the exception of those spec
• salts of hydrazine
• sodium ( R )-2-(2,4-dichlorophenoxy)propionate
• sodium 3,5-bis(3-(2,4-di- tert -pentylphenoxy)propyl
• sodium 3,5-bis(tetradecyloxycarbonyl)benzenesulfinat
• sodium 3-nitrobenzenesulphonate
• sodium 4-(2,4,4-trimethylpentylcarbonyloxy)benzenesu
• sodium 4-(4-chloro-6-( N -ethylanilino)-1,3,5-triazi
• sodium 4-[4-(4-hydroxyphenylazo)phenylamino]-3-nitro
• sodium 4-chloro-1-hydroxybutane-1-sulfonate
• sodium 5- n -butylbenzotriazole
• sodium chromate
• sodium dichromate
• sodium selenite
• spiroxamine (ISO)
• styrene-4-sulfonyl chloride
• succinic anhydride
• sulphanilic acid
• tecnazene (ISO)
• tert -butyl (5 S ,6 R ,7 R )-3-bromomethyl-5,8-dioxo
• tert -butyl (triphenylphosphoranylidene) acetate
• tert -butyl acrylate
• tetra -sodium/lithium 4,4'-bis-(8-amino-3,6-disulfon
• tetrabutylammonium butyltriphenylborate
• tetrachlorophthalic anhydride
• tetrachloroplatinates with the exception of those sp
• tetrakis(tetramethylammonium) 6-amino-4-hydroxy-3-(7
• tetralithium 6-amino-4-hydroxy-3-(7-sulfonato-4-(4-s
• tetramethylene diacrylate
• tetramethylthiuram monosulphide
• tetrasodium ( c -(3-(1-(3-( e -6-dichloro-5-cyanopyr
• tetrasodium 1,2-bis(4-fluoro-6- [5-(1-amino-2-sulfon
• tetrasodium 3,3'-(piperazine-1,4-diylbis((6-chloro-1
• tetrasodium 4-[4-chloro-6-(4-methyl-2-sulfophenylami
• tetrasodium 4-amino-3,6-bis(5-(6-chloro-4-(2-hydroxy
• tetrasodium 5-[4-chloro-6-( N -ethyl-anilino)-1,3,5-
• tetrasodium 5-benzamido-3-(5-(4-fluoro-6-(1-sulphona
• tetrasodium [7-(2,5-dihydroxy-K O 2-7-sulfonato-6-[4
• thionyl chloride, reaction products with 1,3,4-thiad
• thiophanate-methyl (ISO)
• thiram (ISO)
• tin(II) methanesulphonate
• toluene-2,4-diammonium sulphate
• tolylfluanid (ISO)
• trans -4-cyclohexyl-L-proline monohydrochloride
• trans — N -methyl-2-styryl-[4'- aminomethine-(1-acet
• trans-4-phenyl-L-proline
• tri-allate (ISO)
• triadimefon (ISO)
• tributyltetradecylphosphonium tetrafluoroborate
• trichlorfon (ISO)
• trifloxystrobin (ISO)
• trifluralin (ISO) (containing <0.5 ppm NPDA)
• trinickel disulfide
• trisodium (1-(3-carboxylato-2-oxido-5-sulfonatopheny
• trisodium [2-(5-chloro-2,6-difluoropyrimidin-4-ylami
• trisodium bis[(3'-nitro-5'-sulfonato(6-amino-2-[4-(2
• turpentine, oil
• UVCB condensation product of: tetrakis-hydroxymethyl
• valinamide
• vanadyl pyrophosphate
• vinclozolin (ISO)
• zinc bis(dibutyldithiocarbamate)
• zinc bis(diethyldithiocarbamate)
• zinc chromates including zinc potassium chromate
• zineb (ISO)
• ziram (ISO)
• α[2-[[[(2-hydroxyethyl)methylamino]acetyl]amino]prop

Obblighi pratici

Se un prodotto contiene una sostanza di questa classe sopra le soglie pertinenti, la classificazione si riflette su etichetta CLP (pittogramma, avvertenza, indicazioni H, consigli P), scheda dati di sicurezza (sezioni 2 e 15), imballaggio ed eventuale notifica al centro antiveleni. Per le miscele il contributo dipende dalla concentrazione e da eventuali limiti specifici o fattori M.

Altre classi di pericolo salute

Il CLP raggruppa le classi in pericoli fisici, per la salute e per l'ambiente. Altre classi del gruppo «salute»:

• Tossicità acuta (Acute Tox.)
• Corrosione della pelle (Skin Corr.)
• Irritazione cutanea (Skin Irrit.)
• Gravi lesioni oculari (Eye Dam.)
• Irritazione oculare (Eye Irrit.)
• Sensibilizzazione respiratoria (Resp. Sens.)
• Mutagenicità sulle cellule germinali (Muta.)
• Cancerogenicità (Carc.)
• Tossicità per la riproduzione (Repr.)
• Effetti sull’allattamento o attraverso l’allattamento (Lact.)
• Tossicità specifica per organi bersaglio – esposizione singola (STOT SE)
• Tossicità specifica per organi bersaglio – esposizione ripetuta (STOT RE)
• Pericolo in caso di aspirazione (Asp. Tox.)

Fonti

Classe e categorie secondo l'Allegato I e l'Allegato VI del Regolamento (CE) n. 1272/2008 (CLP). Gli elenchi di sostanze derivano dalla Tabella 3.1 dell'Allegato VI; verifica sempre la versione consolidata vigente e l'inventario C&L dell'ECHA.

Domande frequenti

Come faccio a sapere se una sostanza rientra in questa classe?

Si controlla la sua classificazione: nelle schede per sostanza trovi i codici di classe e categoria di pericolo tratti dall'Allegato VI del CLP, oppure si applica l'autoclassificazione sulla base dei dati disponibili.

Questa classe richiede un pittogramma in etichetta?

Sì, quando previsto dalla categoria: in etichetta CLP vanno riportati pittogramma, avvertenza, indicazioni di pericolo (H) e consigli di prudenza (P) coerenti con la classificazione.

Dove ritrovo l'elenco completo delle sostanze sensibilizzazione cutanea?

In questa pagina trovi gli esempi collegati alle schede; l'elenco completo è nell'archivio delle schede CLP per sostanza.

La classificazione può cambiare nel tempo?

Sì: gli ATP (adeguamenti al progresso tecnico) aggiornano l'Allegato VI. Verifica sempre la versione consolidata vigente e l'inventario C&L dell'ECHA.